Product ID:PLV2-2X, CUSTOM PLASMA STANDARD, 1,000 PPM OF(SUPDAT)
MSDS Date:02/27/1991
FSC:6810
NIIN:00N058956
MSDS Number: BXHZM

SPEX INDUSTRIES INC

3880 PARK AVE
EDISON, NJ 08820
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 201-549-7144

Preparer: VANAJA SEVAKUMAR

Cage: 07977

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 07977

NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA) (2% NITRIC

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2-15%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM;4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

VANADIC ACID, AMMONIUM SALT; (AMMONIUM VANADATE) (NH*4VO*3)

CAS: 7803-55-6

RTECS: YW0875000

Fraction By Weight: <0.1%

OSHA PEL 0.05 MG/M3 (V2O5)

ACGIH TLV: 0.05 MG/M3 (V2O5)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BASES WILL CAUSE VIOLENT SPLATTERING.

RTECS: 9999999ZZ

CAUSE DEEP ULCERS & STAIN SKIN BRIGHT

RTECS: 9999999ZZ

TEETH W/PRLNG EXPOS. INGEST OF LIQ WILL CAUSE IMMED

RTECS: 9999999ZZ

BE FATAL CAUSING SPASM, INFLAMM & EDEMA OF LARYNX &

RTECS: 9999999ZZ

SENSATION, COUGH, WHEEZING, LARYNGITIS, SHORTNESS OF

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

HAVE IMMED AVAILABILITY OF AN EYE WASH IN

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 2.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
HOWEVER, SINCE NITRIC ACID IS IN SOLN AT 1%/GREATER, HLTH HAZS FOR
CONC NITRIC ACID ARE GIVEN. THIS SOLN MAY BE HARMFUL IF INHALED,
INGESTED/CONTACTED W/SKIN/EYES. VANADIUM CMPDS CAN AFFECT LIVER,
RESP (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TRACT/SKIN. CONC NITRIC ACID MAY BE
FATAL IF TOO MUCH IS INHALED/ABSORBED THRU SKIN. CONC NITRIC ACID
VAP/MIST IS IRRIT OF EYES, MUC MEMBS & SKIN. IN CONT W/EYES, IT
PRDCES SEV BURNS WHICH MA Y RSLT IN PERM DMG & VISUAL IMPAIRMENT.ON
SKIN, LIQ/CONC VAP PRDCES IMMED, SEV & PENETRATING BURNS; CONC
SOLNS (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAMINATED CLOTHING,
THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING
THOROUGHLY BEFORE RE USE. INHAL:MOVE TO FRESH AIR. INGEST:DONOT
INDUCE VOMITING. GET IMMED MED HELP. IF PERSON IS CONSCIOUS, GIVE
LG QTYS OF WATER/MILK. IF IRRITATION CONTINUES, GET MEDICAL
ATTENTION IMMEDIATELY.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST, BUT IS STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELS FLAMM (SUPP DATA)

Spill Release Procedures:VENTILATE AREA. DILUTE SPILL W/WATER & NEUT
W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR
PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICKUP IS
COMPLETE. WEAR CHEM RESIST GLA SSES, GLOVES & CLTHG. WEAR
NIOSH/MSHA APPRVD RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONC NITRIC ACID WILL ATTACK SOME
FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMPERATURE.
KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE LIQUID. AVOID
INHALATION, INGESTION & CONTACT W/EYES & SKIN.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS (ING 8)
Other Protective Equipment:EMER EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA . WEAR CHEM RESIST CLTHG, LAB COAT. (ING 9)
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:VANADIUM IN 2% NITRIC ACID. EXPLO HAZ:HYDROGEN
GAS. CONC HNO*3 REACTS EXPLOSIVELY W/COMBUST ORG/READILY OXIDIZABLE
MATLS SUCH AS; ALCOHOL, WOOD, TURPENTINE, METAL POWDERS, HYD ROGEN
SULFIDE, ETC. MATLS TO AVOID:ALCOHOL, WOOD, TURPENTINE, METAL
POWDERS, HYDROGEN SULFIDE, ETC. CONT W/STRONG(ING 3)

Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS; (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.

Waste Disposal Methods:CONTACT FEDERAL, STATE & LOCAL HAZARDOUS OR
CHEMICAL WASTE DISPOSAL AGENCY FOR REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.